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As can be seen in the chart, structural steel the liquids with the highest vapor pressures have the lowest normal boiling points. Now, do you have a morning or evening routine that helps you kind of perform? A liquid's atmospheric pressure boiling point corresponds to the temperature at which its vapor pressure is equal to the surrounding atmospheric pressure and it is often called the normal boiling point. At the top of Mount Everest, the atmospheric pressure is approximately 0.333 atm, so by using the graph, the boiling point of diethyl ether would be approximately 7.5 °C versus 34.6 °C at sea level (1 atm). The higher the vapor pressure of a liquid at a given temperature, the lower the normal boiling point of the liquid. Note that at higher altitudes, the atmospheric pressure is less than that at sea level, structural steelwork so boiling points of liquids are reduced. Vapor pressure is the pressure of a vapor in equilibrium with its non-vapor phases (i.e., liquid or solid) It also has the lowest normal boiling point (−24.2 °C), which is where the vapor pressure curve of methyl chloride (the blue line) intersects the horizontal pressure line of one atmosphere (atm) of absolute vapor pressure.